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41.
Katsonis N Vicario J Kudernac T Visser J Pollard MM Feringa BL 《Journal of the American Chemical Society》2006,128(48):15537-15541
The structure of molecular monolayers formed at the interface between atomically flat surfaces and a solution of free-base meso-tetradodecylporphyrins (H2Ps) was examined by scanning tunneling microscopy (STM) at the liquid/solid interface. On the surface of graphite (HOPG), H2Ps form a well-ordered monolayer characterized by an oblique unit cell. On Au(111), H2Ps form a self-organized monolayer comprised of two distinct domain types. In both types of domains, the density of the porphyrin cores is increased in comparison to the arrangement observed on HOPG. Also, high-resolution STM images reveal that, in contrast to what is observed on HOPG, physisorption on Au(111) induces a distortion of the porphyrin macrocycle out of planarity. By using X-ray photoelectron spectroscopy, we demonstrate that this is likely to be due to the coordination of the lone pairs of the iminic (-C=N-) nitrogen atoms of the porphyrin macrocycle to Au(111). 相似文献
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Adamczyk K Candelaresi M Kania R Robb K Bellota-Antón C Greetham GM Pollard MR Towrie M Parker AW Hoskisson PA Tucker NP Hunt NT 《Physical chemistry chemical physics : PCCP》2012,14(20):7411-7419
The ultrafast equilibrium fluctuations of the Fe(III)-NO complex of a single point mutation of Myoglobin (H64Q) have been studied using Fourier Transform 2D-IR spectroscopy. Comparison with data from wild type Myoglobin (wt-Mb) shows the presence of two conformational substates of the mutant haem pocket where only one exists in the wild type form. One of the substates of the mutant exhibits an almost identical NO stretching frequency and spectral diffusion dynamics to wt-Mb while the other is distinctly different in both respects. The remarkably contrasting dynamics are largely attributable to interactions between the NO ligand and a nearby distal side chain which provides a basis for understanding the roles of these side chains in other ferric haem proteins. 相似文献
44.
A.A. Stashkevich Y. Roussigné P. Djemia Y. Yushkevich S.M. Chérif P.R. Evans A.P. Murphy W.R. Hendren R. Atkinson R.J. Pollard A.V. Zayats 《Journal of magnetism and magnetic materials》2012
We report the investigations of spin wave modes of arrays of Ni and Co nanorods using Brillouin light scattering. We have revealed the significant influence of spin wave modes along the nanorod axis in contrast to infinite magnetic nanowires. Unusual optical properties featuring an inverted Stokes/anti-Stokes asymmetry of the Brillouin scattering spectra have been observed. The spectrum of spin wave modes in the nanorod array has been calculated and compared with the experiment. Experimental observations are explained in terms of a combined numerical–analytical approach taking into account both the low aspect ratio of individual magnetic nanorods and dipolar magnetic coupling between the nanorods in the array. The optical studies of spin-wave modes in nanorod metamaterials with low aspect ratio nanorods have revealed new magnetic and magneto-optical properties compared to continuous magnetic films or infinite magnetic nanowires. Such magnetic artificial materials are important class of active metamaterials needed for prospective data storage and signal processing applications. 相似文献
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R H Brody H G Edwards A M Pollard 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2001,57(6):1325-1338
FT-Raman spectra were collected from fossil resins originating from a variety of geographical locations. The spectral profiles of most of the fossil resins could be related to modern resins containing diterpenoid components with predominantly labdane skeletons. The spectra collected from the fossil resin sample from Borneo differed from other fossil resins and was found to contain triterpenoid components. The differences in the spectral profile of fossil resins containing diterpenoid components are shown to relate to differences in level of maturation rather than geographical origin. FT-Raman spectra of fossil resins cannot be used to distinguish source although the degree of maturation can be used as an indicator to narrow the range of possible geographical origins. 相似文献
47.
H. Kazemi S. T. G. Wootton N. J. Cronin S. R. Davies R. E. Miles R. D. Pollard J. M. Chamberlain D. P. Steenson J. W. Bowen 《International Journal of Infrared and Millimeter Waves》1999,20(5):967-974
Schottky barrier diodes have been integrated into on-chip rectangular waveguides. Two novel techniques have been developed to fabricate diodes with posts suitable for integration into waveguides. One technique produces diodes with anode diameters of the order of microns with post heights from 90 to 125 microns and the second technique produces sub-micron anodes with post heights around 20 microns. A method has been developed to incorporate these structures into a rectangular waveguide and provide a top contact onto the anode which could be used as an I.F. output in a mixer circuit. Devices have been fabricated and D.C. characterized. 相似文献
48.
David Pollard 《Nuclear Physics B》1984,241(1):155-172
We demonstrate how supersymmetric theories cancel the appearance of unwanted cosmological constants that arise when considering the quantum behaviour of dimensionallu reduced theories. However the cancellation only works in standard supersymmetric theories if the dimensional reduction is over circular “extra” dimensions. 相似文献
49.
Examination has been made on aged and fresh Ag?Sn alloys and on commercial Cu?Ag?Sn dental alloys. Although x-ray diffractograms of aged Ag?Sn showed only λ Ag?Sn and free silver,119Sn Mössbauer spectra exhibited Sn(IV) oxide also. A low Debye temperature showed the oxide to be in intimate dynamical contact with the metallic matrix. Upon adding mercury, the phases λ1 Ag?Hg and η′ Cu?Sn were observed in a commercial specimen. Conversion-electron spectra of a mercury-coated disk showed the presence of λ2 Sn?Hg and a distribution of line positions smaller than that for particulate amalgams. Internal oxidation was found to prevent amalgamation. 相似文献
50.